Concept in thermodynamics
System:
The system may be defined as any specific portion of universe which is chosen to study the thermodynamics’ properties.
Example:
1) Open vessel containing boiling water
2) Wooden box which is used in physical experiment
Surroundings:
All other part of universe other than system where observation is made known as surrounding.
Boundary:
The real and imaginary out line which separates the system from surrounding is known as boundary.
Types of system:-
1) Open system
2) Closed system
3) Isolated system
1)Open system :-
The system in which exchange both matter as well as energy with its surrounding is known as open system.
Example:-
1) Open vessel’s containing water.
2) Cup of tea
2) Closed
system:-
The system which can exchange only energy but not matter with its surrounding
is known as closed system. Here the
energy is either gained or loss by the system with surrounding but does not
exchange matter.
3) Isolated
system:-
The system cannot
exchange either matter or energy (heat) with its surrounding is called isolated
system.
Example:
- Hot water in thermos
Property of
system:-
Property of
system are generally classified into two type
1)
Extensive property
2)
Intensive property
Extensive
property:-
The property of
system whose magnitude depends upon the quantity of matter present in the
system is known as extensive property.
Example:
-
1)
Mass
2) Volume 3) Energy. 4) Heat capacities 5) Number of moles
Intensive
property:-
The property of
system whose magnitude is independent of the quantity of matter present in the
system is known as Intensive property.
Example:-
1)
Temperature. 2) Density
3) Melting point 4) Viscosity 5) Refractive index
6) Melting
point
State variable;
Every system has a
certain measurable thermodynamics properties such as temp. Pressure and volume
this property are state variable.
State of system: -
State of system is defined by
specifying the values of state variable like temp. Pressure, volume etc
If any one of these property changed
then there will be change in a state of system.
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